Thermodynamic Properties of Cuprous Chloride-Potassium Chloride Molten Salt
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چکیده
منابع مشابه
Equation of State and Thermodynamic Properties of Molten Potassium Chloride to 1320 K and 6 kbar
From the Tait equation an equation of state containing five adjustable parameters was developed which fits experimental density data of molten potassium chloride to 1320 K and 6 kbar with a standard deviation of 0.04%. The thermal expansion coefficient, isothermal compressibility, internal pressure, and molar heat capacities at constant pressure and constant volume were calculated as functions ...
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The dependence of indium electro de potential vs. log. concentration of indium (III) is linear and the slopes determined are comparable with the slopes calculated from the Nernst equation, assuming n = 3. The potential of In/ln(III) has been determined to be 0.805 ± 0.003 V with respect to Pt/PtC12 (1 M). At 693 K the free energy of formation of the indium(III) chloride in a 1 M solution is -32...
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Molybdenum(VI) oxide reacts with molten LiC1-KCI eutectie at 450 ~ to form MOO2C12, which probably is present as an anion MoO2Cl4 =, and pyromolybdate, Mo207 =. Both of these species are electrochemically reduced to MOO2, which can be reoxidized to MoO2CI2 by current reversal. A second reduction step, observed whether MoO3 or Mo2072is added to the melt, can be attributed to the reduction of MoO...
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Chronopotent iometry of chromate in the presence of NiC12 in molten LiCIKCI eutectic reveals a diffusion controlled, three electron reduct ion step. In the presence of excess NiC12, chromate is reduced at --0.35V vs. P t ( I I ) / P t reference electrode and the electroactive species responsible for the chronopotentiometric wave is estimated to have a diffusion coefficient of 1.06 9 10 -5 cm 2 ...
متن کاملDensity of Molten Terbium Chloride
Anhydrous (99.99%) TbCl3 was obtained from Aldrich (Milwaukee, WI, USA) and used without further purifications. It was handled in an argon-filled dry box with a water content < 2 ppm and an oxygen content < 1 ppm. A 166Ho radiation source (2.27 MBq) was used because of its desirable decay characteristics (t1/2 = 1200y, up to 8 photons per disintegration, more than 10% branching ratio). A multi-...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1968
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.71.9_1445